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Electrochemical kinetic parameters of a metal hydride battery electrode

Identifieur interne : 000163 ( France/Analysis ); précédent : 000162; suivant : 000164

Electrochemical kinetic parameters of a metal hydride battery electrode

Auteurs : M. Tliha [Tunisie] ; H. Mathlouthi [Tunisie] ; Jilani Lamloumi [Tunisie] ; A. Percheron-Guegan [France]

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RBID : Pascal:07-0305978

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Abstract

The electrochemical properties of the LaNi3.55Mn0.4Al0.3Co0.4Fe0.35 electrode were investigated using the micropolarization measurements. The exchange current density, the polarization resistance, and the equilibrium potential were determined as a function of the state of charge (SOC) in the electrode. The micropolarization measurements indicated that the electrochemical kinetic property was improved with increasing SOC, due to the increase of the electrocatalytic activation of the surface and the increase of the hydrogen diffusivity in the alloy bulk.


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Pascal:07-0305978

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<term>Activation</term>
<term>Current density</term>
<term>Electric batteries</term>
<term>Electrochemical properties</term>
<term>Equilibrium potential</term>
<term>Hydrogen</term>
<term>Hydrogen storage</term>
<term>Lanthanum Nickel Manganese Aluminium Cobalt Iron Hydrides</term>
<term>Measurement</term>
<term>Metal Hydrides</term>
<term>State of charge</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Batterie électrique</term>
<term>Métal Hydrure</term>
<term>Lanthane Nickel Manganèse Aluminium Cobalt Fer Hydrure</term>
<term>Propriété électrochimique</term>
<term>Mesure</term>
<term>Densité courant</term>
<term>Potentiel équilibre</term>
<term>Activation</term>
<term>Hydrogène</term>
<term>Etat charge</term>
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<div type="abstract" xml:lang="en">The electrochemical properties of the LaNi
<sub>3.55</sub>
Mn
<sub>0.4</sub>
Al
<sub>0.3</sub>
Co
<sub>0.4</sub>
Fe
<sub>0.35</sub>
electrode were investigated using the micropolarization measurements. The exchange current density, the polarization resistance, and the equilibrium potential were determined as a function of the state of charge (SOC) in the electrode. The micropolarization measurements indicated that the electrochemical kinetic property was improved with increasing SOC, due to the increase of the electrocatalytic activation of the surface and the increase of the hydrogen diffusivity in the alloy bulk.</div>
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